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Titanium and Copper-Nickel Construction

Seawater service: titanium ignores it, copper-nickel handles it

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U-Tube Heat Exchangers For

Titanium and Copper-Nickel Construction
U-Tube Duty

Seawater defeats most alloys eventually. Titanium ignores it entirely. Copper-nickel handles it well within a velocity band that has to be respected in both directions.

Titanium Grade 2. Effectively immune to chloride attack including seawater, brine and hypochlorite, at any concentration and across the temperature range these exchangers see. It is thin-walled and light, so the cost per square foot is considerably less punishing than the price per pound implies.

Copper-nickel. 90/10 and 70/30 alloys have long been standard in seawater service, and they carry a genuine advantage in biofouling resistance because copper ions discourage marine growth. The constraint is velocity: too high and the protective film erodes away, too low and deposits form and cause under-deposit attack.

Velocity Is the Copper-Nickel Constraint. Copper-nickel relies on a protective surface film. Exceed the alloy's velocity limit and that film erodes faster than it reforms, producing erosion-corrosion that concentrates at tube inlets and at any local turbulence.

Run too slow and the opposite problem appears: deposits settle, and corrosion proceeds underneath them where the film cannot maintain itself. The result is a design window rather than a maximum, and it has to be checked against turndown as well as design flow.

titanium and copper-nickel construction process diagram

Galvanic care. Titanium is noble relative to almost everything, so pairing it with carbon steel or copper alloys in a wetted joint accelerates attack on the less noble metal. Tubesheet material and any sacrificial protection have to be considered together with the tube choice.

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Two Answers to Seawater

Seawater defeats most alloys eventually. Titanium ignores it entirely; copper-nickel handles it well within a velocity band that has to be respected in both directions. Titanium is noble relative to almost everything, so the tubesheet material and any sacrificial protection have to be considered together with the tube choice.

Titanium Grade 2

  • Effectively immune to chloride attack
  • Seawater, brine and hypochlorite at any concentration
  • Thin-walled and light
  • Cost per square foot lower then the price per pound implies
  • Bends well, springs back differently

Copper-Nickel 90/10 & 70/30

  • Long-standing seawater standard
  • Copper ions discourage marine growth
  • Relies on a protective surface film
  • Too fast erodes the film; too slow allows deposits
  • Design window checked at turndown as well as design flow

Galvanic Care

  • Titanium is noble to almost every other metal
  • Pairing with carbon steel or copper alloys accelerates attack
  • Tubesheet material chosen with the tube
  • Sacrificial protection where dissimilar metals meet
  • Wetted joints reviewed at design

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